This value suggests that the increase in polymer hydrophobicity provides a significant thermodynamic driving force towards further esterification, perhaps counteracting the buildup of water that was otherwise expected to limit conversion. Assists in troubleshooting SAP transactions; provide support to operations and maintenance. In Ullmans Encyclopedia of Industrial Chemistry. Reduction in life expectancy in Brazil after COVID-19. Advancing sustainable materials management: 2017 fact sheet. Liang, L. et al. Sci. Percentage loss due to COVID-19 mortality relative to increases in female and male e0 (a) and e65 (b) between 2000 and 2020 by state. is supported by the Brazilian National Council for Scientific and Technological Development. Google Scholar. ADS Demography 43, 647657 (2006). ACS Macro Lett. Geyer, R., Jambeck, J. R. & Law, K. L. Production, use, and fate of all plastics ever made. First reported cases of SARS-CoV-2 sub-lineage B.1.617.2 in Brazil: an outbreak in a ship and alert for spread. Quantifying impacts of the COVID-19 pandemic through life expectancy losses: a population-level study of 29 countries. LIFE-2022-SAP-NAT Nature and Biodiversity - Standard Action Projects (SAP) Phillips, T. Covid eruption in Brazils largest state leaves health workers begging for help. J. Moreover, mechanical recycling cannot be used with polymers that do not reversibly melt (e.g., crosslinked polymers). J. Adhes. In 15 states (including the entire Southeast region), this loss was higher among males (Fig. Lotta, G., Wenham, C., Nunes, J. Bjrn, A., Owsianiak, M., Molin, C. & Laurent, A. in Life Cycle Assessment: Theory and Practice; (eds) Hauschild, M. Z., Rosenbaum, R. K., Olsen, S. I. & Pimenta, D. N. Community health workers reveal COVID-19 disaster in Brazil. Sci. Ultimately, inequality might become worse, exacerbating an already distressing scenario due to COVID-19. Characterisation of the first 250,000 hospital admissions for COVID-19 in Brazil: a retrospective analysis of nationwide data. Natl Acad. Moreover, the life cycle assessments, which utilized soiled diapers as the starting point, demonstrated that these open-loop recycling methods outperform the conventional routes from petroleum-derived feedstocks on nearly every metric, including for the key LCA metrics of global warming potential and cumulative energy demand. We approximated the population at risk in 2021 by interpolating IBGE population projections to the mid-analysis period (1 March 2021). Adoption is complex, emotional, life-altering. 19, 36923706 (2017). Al-Jabari, M., Abu Ghyadah, R. & Alokely, R. Recovery of hydrogel from baby diaper wastes and its application for enhancing soil irrigation management. https://www.epa.gov/sites/production/files/2019-11/documents/2017_facts_and_figures_fact_sheet_final.pdf (2019). The materials, equipment, synthetic methods, as well as all processed data generated in this study are provided in the Supplementary Information file. Revista de Administrao Pblica 54, 678696 (2020). ^c2/rML[,[gs] & Brooks, C. L. Adaptive landscape flattening accelerates sampling of alchemical space in multisite dynamics. On average, larger declines in e0 and e65 were estimated in the North regions and smaller in the South regions (Fig. Proposals under this topic must address EU Nature and Biodiversity legislation compliance assurance and access to justice by:- establishing new or, where in place, enhancing existing cross-border, national or regional networks of compliance assurance practitioners or experts; and/or establishing or, where in place, improving professional Clean. Netball news: Nat Medhust discusses West Coast Fever return in Team Clean. Res. Liu, Y., Lotero, E. & Goodwin, J. G. Jr Effect of water on sulfuric acid catalyzed esterification. The Kick-off meeting of the LIFE-2021-SAP-NAT-NATURE TURTLENEST project will be held on January 20 in Rome, at the Legambiente headquarters. The resulting chain-shortened PAAP&G fragments were then dialyzed to remove excess acid, lyophilized, and then ground into a powder. Carlyle, R. L. Process for the production of acrylic acid esters. J. Appl. M.C.C., N.G., T.A. X.iieS(,& Combined, these data indicate that open-loop recycling of the superabsorbent poly(acrylic acid) to synthesize PSAs is both energetically and environmentally favorable compared to petroleum-derived syntheses in our assessment. Abbasi, J. <>/Metadata 190 0 R/ViewerPreferences 191 0 R>> Health 9, e782e792 (2021). Recording of LIFE Infoday session(edition Call 2021- content valid also for call 2022) US Provisional Patent Application No. All authors contributed to the interpretation of results and manuscript editing. Smith, D. W. & Bradshaw, B. S. Variation in life expectancy during the twentieth century in the United States. J. Med. 7 April 2022 - Full Proposal. From an energetic standpoint, the CED is reduced by 18.8% and 18.6% with the sonication scenarios, and further reduced (by 24.8%) in the scenario without sonication. LIFE-2021-SAP-NAT-GOV: Nature Governance - Innovation Place and JavaScript. a, Estimated change in life expectancy at birth in 2020 based on the difference from life tables calculated for 2019 and 2020 by state and sex. Boletim Extraordinrio do Observatrio Covid-19 Fiocruz. Lett. To access more than one type of pressure-sensitive adhesive, we needed a method to shorten the linear polymers obtained after the decrosslinking step. First, we obtained mid-year population projections for 20182020 and abridged life tables estimated for 20002020 by state, age and sex from the Brazilian Institute of Geography and Statistics (Instituto Brasileiro de Geografia e Estatstica, or IBGE, in Portuguese) (https://www.ibge.gov.br/en/statistics/social/population/18176-population-projection.html). These records, aggregated at the state level, are publicly available by date on the website (https://brasil.io/covid19/). I tried to learn Python before,. Brazil does not lack a universal healthcare system, a network of community health agents to target vulnerable communities, sufficient data and a capable cadre of researchers tirelessly advancing knowledge and informing policy. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. . Programme for Environment and Climate Action (LIFE) ID: LIFE-2021-SAP-NAT-NATURE: Types of action: LIFE Project Grants: Deadline model: single-stage: Opening date: 13 July 2021: Deadline date: 30 November 2021 17:00:00 Brussels time . White House cybersecurity strategy stresses software safety x:y*$J*e,=x QHM`zeF i(ED'*V[Xzd;KOtI102e2P\vto\jQ| Z a, Change (in years) in the femalemale gap in e0 and e65 based on the difference from life tables calculated for 2019 and 2020 by state and sex. A facile and highly efficient strategy for esterification of poly(meth)acrylic acid with halogenated compounds at room temperature promoted by 1,1,3,3-tetramethylguanidine. 109, 57555798 (2009). Larger relative femalemale gaps were estimated for e65an increase of 16.3% in 2020 in Brazil and a 107% increase in 2020 in Amap. We made the assumption of proportionality between forces of decrement from cause i (or all causes except i) and the force of decrement from all other causes combined8,45. LIFE-2021-SAP-NAT-NATURE Nature and Biodiversity LIFE-2021-SAP-NAT-GOV Nature Governance Each project application under the call must address only one of these topics. Aburto, J. M. et al. When closed-loop processes are unavailable, an alternative, known as open-loop chemical recycling can be utilized. https://www.petrochemistry.eu/wp-content/uploads/2018/01/150727_EBAM-Eco-profile-Acrylic-Monomers-1.pdf (Cefic European Basic Acrylic Monomers Sector group (EBAM): Brussels, 2015). % Il 13 luglio stato aperto il primo invito a presentare proposte nell'ambito del nuovo programma LIFE 2021-202 7, che comprende quattro sottoprogrammi: natura e biodiversit, economia circolare e qualit della vita, LIFE-2021-SAP-NAT-GOV Nature Governance Standard Action Projects (SAPs) Strategic Nature Projects (SNAPs) SNAPs: (1)target the implementation of the Prioritised Action Frameworks (PAF) other plans or strategies adopted at international, national, regional or multiregional level by nature Part B 52, 873896 (2013). ANDS with Nectar and RDS have a vision in 2018-19 to create the Australian Research Data Cloud - "an integrated data-intensive infrastructure system, incorporating physical infrastructure, policies, data, software, tools and support for researchers." Reduction in life expectancy in Brazil after COVID-19 - Nature 2). Get the most important science stories of the day, free in your inbox. Khoo, S. C. et al. Thus, we estimated total deaths in 2021, inclusive of COVID-19 deaths, as \({\,}_nD_x = ({\,}_nK_x - \,_nD_x^{COV})({\,}_n^ \ast M_x) + \,_nD_x^{COV}\), where \({\,}_nD_x\) is the number of deaths estimated to occur in 2021 in the age range x to x + n; \({\,}_nK_x\) is the population at risk in the age range x to x + n; \({\,}_n^ \ast M_x\) are age-specific mortality rates in the absence of COVID-19 (assumed to be 2019 mortality rates); and \({\,}_nD_x^{COV}\) is the number of confirmed COVID-19 deaths. Lancet 396, 365366 (2020). wrote the first draft of the manuscript. & van der Schaar, M. Ethnic and regional variations in hospital mortality from COVID-19 in Brazil: a cross-sectional observational study. This approach was inspired by the similar structures of sodium polyacrylate (superabsorbent polymer) and the polyacrylates (pressure-sensitive adhesives) used in tapes, bandages, and sticky notes, among others23. Surprisingly, even when excess H2O was intentionally added (3 equiv), high conversions were still observed (Supplementary Information pgs S15S16). Next, we estimated total 2021 deaths, including COVID-19 confirmed deaths (\({\,}_nD_x^{COV}\)), reported by Brasil.io. Decrosslinking has been reported using ozonolysis16, though not for the purposes of mechanical recycling. Process Saf. Fifth, reductions in the health budget and changes in the health financing model are likely to affect health outcomes40. Barbosa, R. J., Souza, P. H. G. F. & Soares, S. S. D. Distribuio de Renda nos Anos 2010: uma dcada perdida para desigualdade e pobreza. California, United States. 4, 28912897 (2013). The dataset provides the age and sex structure of hospitalized COVID-19 deaths, and frequent updates are made publicly available by the Ministry of Health (https://opendatasus.saude.gov.br/nl/dataset). In the first 4 months of 2021, COVID-19 deaths represented 107% of the total 2020 figures. Everyone involved in adoptionbirthparents, adoptive parents, adoptees, adoption professionals, and beyonddeserves support when they need it. JAMA 325, 808811 (2021). Nature and Biodiversity ). The estimated decline in 2021 e0 is 1.78 years (1.86 years for males and 1.64 years for females). {o"yQr8"2ioFq[V One salient example is the superabsorbent material used in diapers and feminine hygiene products, which contain crosslinked sodium polyacrylates. Publishers note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. 2 Topics under the 2021 call 1. Nature and Biodiversity - axudas.gal Science 360, 2829 (2018). Chemically recyclable polymers: a circular economy approach to sustainability. To probe the role of both solvent and substrate hydrophobicity, we used two different substrates (acetic versus undecanoic acid) and solvents (ethanol versus 2-ethylhexanol). To obtain 29, 233246 (1990). Jul 13, 2021 Nature and Biodiversity ID:LIFE-2021-SAP-NAT-NATURE Type of action: [object Object] Objective: To contribute to European Union objectives for the protection, maintenance and restoration of the Union's natural capital in its marine, freshwater and terrestrial ecosystems. (Wiley-VCH Verlag GmbH & Co, Weinheim, 2020). ISSN 1546-170X (online) Barberia, L. G. & Gmez, E. J. Commercial polyacrylate-based PSAs are often accessed via petroleum-sourced monomers (Fig. Funding call: Nature Governance | EFSA - European Food Safety Authority Collias, D. I. et al. life-2021-sap-nat nature #life 2021 sap env gov #life-2021-sap-nat nature #life 2021 ta pp env sip #Life Call #life programme 2021 #LIFE Program #call for proposals climate change 2021 #life 2021 strat two stage Esterification of carboxylic acids with trialkyloxonium salts. 9w%?>Jb(o.IACt"`. A 245, 132140 (2006). e65 declined by a larger percentage for males than females in all states, reflecting mens higher risks of dying from COVID-19 (ref. Eng. Process for Producing Acrylic Acid. LIFE-2021-SAP-NAT-GOV - Nature Governance LIFE-2021-CET-LOCAL - Technical support to clean energy transition plans and strategies in municipalities and regions LIFE-2021-CET-PDA - Disruptive PDA - Technical Assistance to advance market boundaries for sustainable energy investments We abstracted death data on 18 May 2021, for all states, as reported through 30 April 2021 (n=209,458 confirmed COVID-19 deaths). J. Reaction conditions for base-mediated and acid-catalyzed decrosslinking reactions with LCA comparison. Correspondence to Cite this article. In contrast, few studies have examined recycling of the sodium polyacrylate superabsorbent polymers. March 2, 2023 - 6:00AM. To estimate total deaths in the presence of COVID-19, we used different methodological approaches. Within the first 15h, we observed a substantial drop (more than two orders of magnitude) in viscosity, after which point no further changes were observed. JRSvk] Giving superabsorbent polymers a second life as pressure-sensitive adhesives. This compromised screening for cancer, with a reduction of about 35% in new diagnoses28. From these studies, we conclude that the quantitative esterification of the polymer results from the hydrophobic reaction environment created by the polymer backbone and the 2-ethylhexanol solvent. 8,17). Numbers above 100 indicate more deaths in 2021 than 2020. Specifically, using a 2 or 3 step synthetic process, the sodium polyacrylate is converted into a pressure-sensitive adhesive (PSA), which has a significant global market (expected to be $13 billion by 2023) (https://www.alliedmarketresearch.com/pressure-sensitive-adhesives-market).

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